A monolithic integrated micro direct methanol fuel cell based on sulfo functionalized porous silicon

نویسندگان

  • M. Wang
  • Y. X. Lu
  • L. T. Liu
  • X. H. Wang
چکیده

In this paper, we demonstrate a monolithic integrated micro direct methanol fuel cell (μDMFC) for the first time. The monolithic integrated μDMFC combines proton exchange membrane (PEM) and Pt nanocatalysts, in which PEM is achieved by the functionalized porous silicon membrane and 3D Pt nanoflowers being synthesized in situ on it as catalysts. Sulfo groups functionalized porous silicon membrane serves as a PEM and a catalyst support simultaneously. The μDMFC prototype achieves an open circuit voltage of 0.3 V, a maximum power density of 5.5 mW/cm. The monolithic integrated μDMFC offers several desirable features such as compatibility with micro fabrication techniques, an undeformable solid PEM and the convenience of assembly.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Silicon-based Proton Exchange Membrane for Micro Direct Methanol Fuel Cells

This paper presents our research on silicon-based proton exchange membranes for siliconbased micro fuel cell applications. The porous silicon membranes with a thickness of 20-40 m were fabricated. And the porous silicon-based proton exchange membranes were formed by using the combination of the porous silicon membranes and Nafion solution. The proton conductivities of the porous silicon-based P...

متن کامل

Design and Fabrication of a Silicon-based Micro Direct Methanol Fuel Cell Stack

This paper presents a silicon-based micro direct methanol fuel cell (μDMFC) stack with compact stacked structure and a unique shared anode plate. The μDMFC stack consists of two fuel cells in electrically parallel connection, while the fuel transport is arranged in series. Experimental results show that the μDMFC stack generates a power density of 12.71mW/cm, almost twice as much as that of a s...

متن کامل

Functionalized and Electrospun Polymeric Materials as High-Performance Membranes for Direct Methanol Fuel Cell: A Review

Proton exchange membranes (PEM) for a direct methanol fuel cell (DMFC) have main drawbacks which are methanol permeability, reduced proton conductivity and the cost of the membrane. This paper reviews different polymeric materials such as fluorinated, non-fluorinated, acid-base complex, and composite membranes for DMFC. Currently, nonfluorinated membranes gain a lot of atte...

متن کامل

Modified CNTs/Nafion composite: The role of sulfonate groups on the performance of prepared proton exchange methanol fuel cell’s membrane

A novel Nafion®-based nanocomposite membrane was synthesized to be applied as direct methanol fuel cells (DMFCs). Carbon nanotubes (CNTs) were coated with a layer of silica and then reacted by chlorosulfonic acid to produce sulfonate-functionalized silicon dioxide coated carbon nanotubes (CNT@SiO2-SO3H). The functionalized CNTs were then introduced to Nafion®, and subsequently, methanol permeab...

متن کامل

Porous Proton Exchange Membrane Based Zeolitic Imidazolate Framework-8 (ZIF-8)

Metal-organic frameworks (MOFs) are emerging material class for the past few years due to its tailorability characteristics for various applications. However, the research and development (R&D) of MOFs is still scarce for fuel cell system. This may be due to the several difficulties faced in selecting a good MOFs-based electrolyte, which consequently affects both proton conduction and methanol ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016